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Daniela Wirth-Hamdoune, Dr. Stefan Ullrich, Dr. Ute Scheffer, Toni Radanović, Dr. Gerd D&rner andProf. Dr. Michael W. G&bel*DOI:&10.1002/cbic.
ChemBioChem pages 506&514, Author InformationInstitut f&r Organische Chemie und Chemische Biologie, Johann Wolfgang Goethe-Universit&t Frankfurt, Frankfurt am Main, GermanyEmail: Prof. Dr. Michael W. G&bel (M.Goebel@chemie.uni-frankfurt.de)Publication HistoryIssue online: 15 MAR 2016Version of Record online: 16 FEB 2016Accepted manuscript online: 8 JAN AM ESTManuscript Received: 22 OCT 2015
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DNAnucleic acidsAbstractBis(guanidinium)alcohols have been designed to react with phosphodiester substrates in a fast transphosphorylation step, a quasi-intramolecular process taking place in contact ion pairs. Here the attachment of such compounds to Dervan-type hairpin polyamides is described. The resulting conjugate 1 binds to AT-rich DNA duplexes with affinity similar to that of the parent polyamide as shown by UV melting experiments and CD titrations. Conjugate 1 nicks plasmid DNA at concentrations ranging from micromolar to high nanomolar.This service is more advanced with JavaScript available, learn more at
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